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HERO ID
1181656
Reference Type
Journal Article
Title
INTRINSIC REACTIVITIES OF SOME CARBANIONS IN SIGMA-ADDUCT FORMING REACTIONS
Author(s)
Crampton, MR; Stevens, JA
Year
1991
Is Peer Reviewed?
Yes
Journal
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry
ISSN:
0300-9580
Publisher
ROYAL SOC CHEMISTRY
Location
CAMBRIDGE
Issue
11
Page Numbers
1715-1720
Language
English
DOI
10.1039/p29910001715
Web of Science Id
WOS:A1991GQ80200012
Abstract
Kinetic and equilibrium data are reported for nucleophilic attack in methanol at unsubstituted ring-positions of 1,3,5-trinitrobenzene, 2,4,6-trinitrotoluene and 1-chloro-2,4,6-trinitrobenzene by carbanions derived from dimethyl malonate, ethyl cyanoacetate and 4-nitro-, 4-cyano- and 2-cyanobenzyl cyanides. The results are used to determine intrinsic reactivities for the carbanions in these sigma-adduct forming reactions and are discussed in terms of the electronic and solvent reorganisation occurring during reaction.
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IRIS
•
Methanol (Non-Cancer)
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WOS
OPPT
•
Malonates
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WOS (private)
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