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HERO ID
1207254
Reference Type
Journal Article
Title
ULTRAFAST RELAXATION IN THE FLUORESCENT STATE OF THE LASER-DYE DCM
Author(s)
Easter, DC; Baronavski, AP
Year
1993
Is Peer Reviewed?
Yes
Journal
Chemical Physics Letters
ISSN:
0009-2614
Volume
201
Issue
1-4
Page Numbers
153-158
Web of Science Id
WOS:A1993KF37900026
Abstract
Ultrafast relaxation in the fluorescent state of 4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran (DCM) has been interrogated by time-resolved femtosecond absorption spectroscopy both in methanol and in ethylene glycol. Following a subpicosecond rise, each frequency-specific trace in ethylene glycol exhibits either a slower increase or a slower decrease in transmission; an additional long-term decay is seen in methanol solution. The data are generally consistent with recent solvation dynamics studies that employed different probe molecules, but the solvation time we measure for ethylene glycol is an order of magnitude shorter than previously reported.
Tags
•
Methanol (Non-Cancer)
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