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HERO ID
1256785
Reference Type
Journal Article
Title
Nanostructured bilayered vanadium oxide electrodes for rechargeable sodium-ion batteries
Author(s)
Tepavcevic, S; Xiong, H; Stamenkovic, VR; Zuo, X; Balasubramanian, M; Prakapenka, VB; Johnson, CS; Rajh, T
Year
2012
Is Peer Reviewed?
1
Journal
ACS Nano
ISSN:
1936-0851
EISSN:
1936-086X
Volume
6
Issue
1
Page Numbers
530-538
Language
English
PMID
22148185
DOI
10.1021/nn203869a
Web of Science Id
WOS:000299368300064
Abstract
Tailoring nanoarchitecture of materials offers unprecedented opportunities in utilization of their functional properties. Nanostructures of vanadium oxide, synthesized by electrochemical deposition, are studied as a cathode material for rechargeable Na-ion batteries. Ex situ and in situ synchrotron characterizations revealed the presence of an electrochemically responsive bilayered structure with adjustable intralayer spacing that accommodates intercalation of Na(+) ions. Sodium intake induces organization of overall structure with appearance of both long- and short-range order, while deintercalation is accompanied with the loss of long-range order, whereas short-range order is preserved. Nanostructured electrodes achieve theoretical reversible capacity for Na(2)V(2)O(5) stochiometry of 250 mAh/g. The stability evaluation during charge-discharge cycles at room temperature revealed an efficient 3 V cathode material with superb performance: energy density of ~760 Wh/kg and power density of 1200 W/kg. These results demonstrate feasibility of development of the ambient temperature Na-ion rechargeable batteries by employment of electrodes with tailored nanoarchitectures.
Keywords
nanostructured electrodes; electrochemical deposition; bilayered V2O5; sodium-ion battery
Tags
IRIS
•
Vanadium Compounds - Problem Formulation
Literature Search: Jan 2010 - Mar 2019
PubMed
WoS
Combined data set
Excluded by SWIFT Review screen
•
Vanadium Inhalation
Literature Search: Jan 2010 – Mar 2019
PubMed
WoS
Combined Dataset
Excluded by SWIFT Review screen
•
Vanadium Pentoxide (Draft, 2011)
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