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Citation
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HERO ID
2510792
Reference Type
Journal Article
Title
Heterogeneous catalytic ozonation of dibutyl phthalate in aqueous solution in the presence of iron-loaded activated carbon
Author(s)
Huang, Y; Cui, C; Zhang, D; Li, L; Pan, D
Year
2015
Is Peer Reviewed?
Yes
Journal
Chemosphere
ISSN:
0045-6535
EISSN:
1879-1298
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Location
OXFORD
Book Title
Chemosphere. 2015, Jan; 119:295-301. [Chemosphere]
Volume
119
Page Numbers
295-301
Language
English
PMID
25036944
DOI
10.1016/j.chemosphere.2014.06.060
Web of Science Id
WOS:000347739600040
URL
http://www.sciencedirect.com/science/article/pii/S0045653514008078
Exit
Abstract
Iron-loaded activated carbon was prepared and used as catalyst in heterogeneous catalytic ozonation of dibutyl phthalate (DBP). The catalytic activity of iron-loaded activated carbon was investigated under various conditions and the mechanisms of DBP removal were deduced. Characterization of catalyst indicated that the iron loaded on activated carbon was mainly in the form of goethite, which reduced its surface area, pore volume and pore diameter. The presence of metals on activated carbon positively contributed to its catalytic activity in ozonation of DBP. Iron loading content of 15% and initial water pH of 8 achieved highest DBP removal among all the tried conditions. Catalyst dosage of 10mgL(-1) led to approximately 25% of increase in DBP (initial concentration 2mgL(-1)) removal in 60min as compared with ozone alone, and when catalyst dosage increased to 100mgL(-1), the DBP removal was further improved by 46%. Based on a comparison of reaction rates for direct and indirect transformation of DBP, the increased removal of DBP in this study likely occurred via transformation of ozone into hydroxyl radicals on the catalyst surface.
Keywords
Carbon/chemistry; Catalysis; Dibutyl Phthalate/chemistry; Iron/chemistry; Ozone/chemistry; Solutions; Water Pollutants, Chemical/chemistry; Water Purification; Degradation mechanism; Dibutyl phthalate; Heterogeneous catalytic ozonation; Iron-loaded activated carbon; 2286E5R2KE; 66H7ZZK23N; 7440-44-0; E1UOL152H7
Tags
IRIS
•
Dibutyl Phthalate (DBP)
Database Searches
Pubmed
Litsearch September 2014 - February 2015
Pubmed
LitSearch Jan 2014 - Sep 2014
PubMed
Excluded: No Primary Data on Health Effects
Use in sample prep or assay
Chemical/physical properties
NAAQS
•
ISA-Ozone (2020 Final Project Page)
Literature Search Results
Literature Search - Excluded
Keyword Search Excluded
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