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HERO ID
2534608
Reference Type
Journal Article
Title
Gas/particle partitioning of PCDD/F compounds in the atmosphere of Istanbul
Author(s)
Saral, A; Gunes, G; Karadeniz, A; Goncaloglu, BI
Year
2015
Is Peer Reviewed?
Yes
Journal
Chemosphere
ISSN:
0045-6535
EISSN:
1879-1298
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Location
OXFORD
Volume
118
Page Numbers
246-252
Language
English
PMID
25290170
DOI
10.1016/j.chemosphere.2014.09.039
Web of Science Id
WOS:000346953700034
URL
https://linkinghub.elsevier.com/retrieve/pii/S0045653514011060
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Abstract
Gas/particle partitioning of polychlorinated dibenzo-p-dioxin (PCDD) and polychlorinated dibenzofuran (PCDF) compounds in the ambient atmosphere were investigated at three different sites (urban-industrial, urban and sub-urban) in İstanbul. Average gas and particle phase concentrations were measured as 133fgm(-3) and 1605fgm(-3), respectively. Gas phase concentrations of polychlorinated dibenzo-p-dioxin/furan (PCDD/F) compounds were determined to be 128fgm(-3), 50fgm(-3), 153fgm(-3) during summer season and 204fgm(-3), 164fgm(-3), 154fgm(-3) during winter season for the respective three sampling sites. Particle phase concentrations were determined to be 287fgm(-3), 176fgm(-3), 160fgm(-3) during summer and 6586fgm(-3), 2570fgm(-3) and 1861fgm(-3) during winter season for those three sampling sites. Chlorination level and molecular weight of congeners affected gas/particle partitioning of PCDD/F compounds. Gas phase percentages of 2,3,7,8-TCDD and OCDD concentrations were determined to be 47% and 1% respectively. A relatively high correlation was found between total particle matter (TPM) and particle phase PCDD/F concentration during winter season.
Keywords
PCDD; PCDF; Atmospheric sampling; Gas/particle partitioning; Urban atmosphere
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