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4066495 
Journal Article 
Petroleum mass removal from low permeability sediment using air sparging/soil vapor extraction: impact of continuous or pulsed operation 
Kirtland, BC; Aelion, CM 
2000 
Journal of Contaminant Hydrology
ISSN: 0169-7722
EISSN: 1873-6009 
41 
3-4 
367-383 
English 
Air sparging and soil vapor extraction (AS/SVE) are innovative remediation techniques that utilize volatilization and microbial degradation to remediate petroleum spills from soils and groundwater, This in situ study investigated the use of AS/SVE to remediate a gasoline spill from a leaking underground storage tank (UST) in the low permeability, clayey soil of the Appalachian Piedmont. The objectives of this study were to evaluate AS/SVE in low permeability soils by quantifying,petroleum mass removal rates, monitoring vadose zone contaminant levels, and comparing the mass extraction rates of continuous AS/SVE to 8 and 24 h pulsed operation. The objectives were met by collecting AS/SVE exhaust gas samples and vadose zone air from multi-depth soil vapor probes. Samples were analyzed for O-2, CO2, BTEX (benzene, toluene, ethylbenzene, xylene), and total combustible hydrocarbon (TCH) concentrations using portable hand meters and gas chromatography. Continuous AS/SVE was effective in removing 608 kg of petroleum hydrocarbons from low permeability soil in 44 days (14.3 kg day(-1)). Mass removal rates ranged from 2.6 times higher to 5.1 times lower than other AS/SVE studies performed in sandy sediments. BTEX levels in the vadose zone were reduced from about 5 ppm to 1 ppm. Ten pulsed AS/SVE tests removed 78 kg in 23 days and the mean mass removal rate (17.6 kg day(-1)) was significantly higher than the last 15 days of continuous extraction; Pulsed operation may be preferable to continuous operation because of increased mass removal and decreased energy consumption. (C) 2000 Elsevier Science B.V. All rights reserved. 
soil venting; bioventing; petroleum remediation; AS/SVE; soil treatment