SYNTHESIS AND REACTIVITY OF SOME 1,2,4-TRIAZOLO[4,3-B]PYRIDAZINE DERIVATIVES

Baloniak, S; Katrusiak, A

HERO ID

4075193

Reference Type

Journal Article

Year

1994

HERO ID 4075193
In Press No
Year 1994
Title SYNTHESIS AND REACTIVITY OF SOME 1,2,4-TRIAZOLO[4,3-B]PYRIDAZINE DERIVATIVES
Authors Baloniak, S; Katrusiak, A
Journal Polish Journal of Chemistry
Volume 68
Issue 4
Page Numbers 683-691
Abstract The triazolo[4,3-b]pyridazine derivatives were obtained in the reaction of 3-chloro-6-hydrazinopyridazine with acetic acid and ethyl chloroformate. Acting on 6-chloro-3-methyl-1,2,4-triazolo[4,3-b]pyridazine with phosphorus pentachloride, a methyl group in position 3 has unexpectedly been exchanged by chlorine. The mechanism of fusing the triazole ring to the pyridazine system has been studied by the reaction of 3-chloro-6-hydrazinopyridazine with formaldehyde, acetaldehyde, and treatment the resulting Schiff bases by bromine in acetic acid with sodium acetate added.
Wosid WOS:A1994NE92200005
Url <Go to ISI>://WOS:A1994NE92200005
Is Certified Translation No
Dupe Override No
Is Public Yes
Keyword 1,2,4-TRIAZOLO[4,3-B]PYRIDAZINES; NUCLEOPHILIC SUBSTITUTION; CYCLIZATION MECHANISM