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4321580 
Journal Article 
beta-Diketimine appended periodic mesoporous organosilica as a scaffold for immobilization of palladium acetate: An efficient green catalyst for Wacker type reaction 
Borah, P; Zhao, Y 
2014 
Yes 
Journal of Catalysis
ISSN: 0021-9517
EISSN: 1090-2694 
318 
43-52 
English 
WOS:000343360800005 
A series of β-diketimine appended periodic mesoporous organosilicas (PMOs) were prepared and characterized. These PMOs were found to be an excellent scaffold for the immobilization of palladium acetate [Pd(OAc)2] through the complexation between Pd(OAc)2 and iminic nitrogen atoms of β-diketiminate, leading to the formation of efficient heterogeneous catalysts (Pd/PMOs) for the oxidation of styrene. Catalytic evaluations show that, in liquid phase using H2O2 as oxidant, Pd/PMOs could promote styrene to undergo Wacker type reaction with a high selectivity of up to 100% toward the formation of acetophenone, a useful chemical with high demand in the global market. The novel solid catalyst offers a good catalytic recyclability with consistently high catalytic activity. In addition, it was experimentally demonstrated that H2O2 plays an important role to prevent unwanted catalyst deactivation. Thus, the current work presents a convenient approach for the direct production of acetophenone from styrene. © 2014 Elsevier Inc. All rights reserved. 
beta-Diketimine; Heterogeneous catalysis; Palladium acetate; Periodic mesoporous silica; Wacker reaction