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Journal Article 
Spatial variations in snowpack chemistry, isotopic composition of NO3- and nitrogen deposition from the ice sheet margin to the coast of western Greenland 
Curtis, CJ; Kaiser, Jan; Marca, A; Anderson, NJ; Simpson, G; Jones, V; Whiteford, E 
ISSN: 1726-4170
EISSN: 1726-4189 
is supplemented by 4386745 : Supplemental materials
The relative roles of anthropogenic nitrogen (N) deposition and climate change in causing ecological change in remote Arctic ecosystems, especially lakes, have been the subject of debate over the last decade. Some palaeoecological studies have cited isotopic signals (delta N-15)) preserved in lake sediments as evidence linking N deposition with ecological change, but a key limitation has been the lack of co-located data on both deposition input fluxes and isotopic composition of deposited nitrate (NO3-). In Arctic lakes, including those in western Greenland, previous palaeolimnological studies have indicated a spatial variation in delta(N-15) trends in lake sediments but data are lacking for deposition chemistry, input fluxes and stable isotope composition of NO3-. In the present study, snowpack chemistry, NO3- stable isotopes and net deposition fluxes for the largest ice-free region in Greenland were investigated to determine whether there are spatial gradients from the ice sheet margin to the coast linked to a gradient in precipitation. Late-season snowpack was sampled in March 2011 at eight locations within three lake catchments in each of three regions (ice sheet margin in the east, the central area near Kelly Ville and the coastal zone to the west). At the coast, snowpack accumulation averaged 181mm snow water equivalent (SWE) compared with 36mm SWE by the ice sheet. Coastal snowpack showed significantly greater concentrations of marine salts (Na+, Cl-, other major cations), ammonium (NH4+; regional means 1.4-2.7 mu mol L-1), total and non-sea-salt sulfate (SO42-; total 1.8-7.7, non-sea-salt 1.0-1.8 mu mol L-1/than the two inland regions. Nitrate (1.5-2.4 mu mol L-1/showed significantly lower concentrations at the coast. Despite lower concentrations, higher precipitation at the coast results in greater net deposition for NO3- as well as NH4+ and non-sea-salt sulfate (nss-SO42-) relative to the inland regions (lowest at Kelly Ville 6, 4 and 3; highest at coast 9, 17 and 11 mol ha(-1) a(-1) of NO3-, NH4+ and nss-SO42- respectively). The delta(N-15) of snowpack NO3- shows a significant decrease from inland regions (5.7 parts per thousand at Kelly Ville) to the coast (-11.3 parts per thousand). We attribute the spatial patterns of delta(N-15) in western Greenland to post-depositional processing rather than differing sources because of (1) spatial relationships with precipitation and sublimation, (2) within catchment isotopic differences between terrestrial snowpack and lake ice snowpack, and (3) similarities between fresh snow (rather than accumulated snowpack) at Kelly Ville and the coast. Hence the delta(N-15) of coastal snowpack is most representative of snowfall in western Greenland, but after deposition the effects of photolysis, volatilization and sublimation lead to enrichment of the remaining snowpack with the greatest effect in inland areas of low precipitation and high sublimation losses. 
• ISA NOxSOxPM Ecology (2018)
     Cited in the Second Draft
          Appendix 2