Jump to main content
US EPA
United States Environmental Protection Agency
Search
Search
Main menu
Environmental Topics
Laws & Regulations
About EPA
Health & Environmental Research Online (HERO)
Contact Us
Print
Feedback
Export to File
Search:
This record has one attached file:
Add More Files
Attach File(s):
Display Name for File*:
Save
Citation
Tags
HERO ID
4583202
Reference Type
Journal Article
Title
Ring opening polymerization of styrene oxide initiated with potassium alkoxides and hydroxyalkoxides activated by 18-crown-6: determination of mechanism and preparation of new polyether-polyols
Author(s)
Grobelny, Z; Matlengiewicz, M; Jurek-Suliga, J; Golba, S; Skrzeczyna, K; Kwapulinska, D
Year
2017
Is Peer Reviewed?
1
Journal
Polymer Bulletin
ISSN:
0170-0839
EISSN:
1436-2449
Volume
74
Issue
11
Page Numbers
4763-4780
DOI
10.1007/s00289-017-1976-4
Web of Science Id
WOS:000410445900026
Abstract
It was stated that initiation in ring opening polymerization of styrene oxide depends on the kind of potassium alkoxide activated by 18-crown-6 used. In the presence of potassium methoxide the oxirane ring opening occurs exclusively in the beta-position and not in the beta or alpha position, i.e., contrary to the previous data. A similar result was obtained in the systems initiated with potassium t-butoxide, 2-methylpropoxide and 1-phenylethoxide. Unexpectedly, potassium i-propoxide and 1-methylpropoxide open the oxirane ring in the beta or alpha position. In all polymerizations, deprotonation of methine group in the monomer takes place under the influence of the initiator and in chain transfer reaction to the monomer. It leads to the formation of macromolecules with unsaturated starting group. However, deprotonation of methylene group in the monomer does not occur. Applying of potassium hydroxyalkoxides, i.e., monopotassium salt of dipropylene glycol or tripotassium salt of 2,2,6,6-tetrakis(hydroxymethyl) cyclohexanol it was possible to synthesize PSO-diols and PSO-pentols without unsaturation. Molar masses of polymers (M-n = 1700-4800 Da) are much higher than reported in literature for other anionic systems. Dispersity of polymers is rather low (M-w/M-n = 1.07-1.15) indicating relatively high rate of initiation and cation exchange reaction.
Keywords
ROP; Oxiranes anionic polymerization; Styrene oxide; Potassium alkoxides; Polyether polyols
Tags
OPPT
•
Glycols
Literature Search
Human Health
WOS (private)
Fate
WOS (private)
Environmental Hazard
WOS (private)
Home
Learn about HERO
Using HERO
Search HERO
Projects in HERO
Risk Assessment
Transparency & Integrity