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HERO ID
4598177
Reference Type
Journal Article
Title
Tuning the oxygen reduction reactivity of interconnected porous carbon by incorporation of phosphorus and activity enhancement through blending with 2D metal dichalcogenides materials
Author(s)
Mutyala, S; Rajaram, R; Karuppasamy, D; Suresh, C; Mathiyarasu, J
Year
2018
Is Peer Reviewed?
Yes
Journal
International Journal of Hydrogen Energy
ISSN:
0360-3199
Volume
43
Issue
9
Page Numbers
4738-4745
DOI
10.1016/j.ijhydene.2017.12.009
Web of Science Id
WOS:000428229300054
Abstract
Design and construction of strong oxygen reduction reaction (ORR) electrocatalysts with high activity and durability are the main concerns in proton exchange membrane fuel cells (PEMFCs). In this study, a unique interconnected porous carbon (ICPC) and phosphorus doped ICPC (P-ICPC) were synthesized and utilized as a support matrix for ORR in alkaline medium. The activity of P-ICPC further enhanced by compositing with 2D metal dichalcogenide MoS2 materials through facile hydrothermal method. The structural characterization indicated that the addition of phosphorus created more defective site in the carbon structure. The MoS2/P-ICPC catalyst exhibited enhanced ORR activity, and its performance. is close to commercial Pt/C catalyst with regards to current density and onset potential. The synthesized MoS2/P-ICPC catalyst shows better stability regarding activity even after the 2000 cycles of acceleration test. The electron transfer number (n) obtained for MoS2/P-ICPC is similar to 3.8, indicating that the oxygen reduction reaction proceeds via 4e(-) pathway with the similar kinetics of commercial Pt/C. The current results revealed that the synthesized MoS2/P-ICPC material might be a better catalyst for oxygen reduction reaction. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
Keywords
Interconnected porous carbon; P-doping; MoS2; Oxygen reduction; Defective sites
Tags
IRIS
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Molybdenum
Litsearch 2018
WOS
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