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HERO ID
4684046
Reference Type
Journal Article
Title
Dynamic light scattering study of aggregation in aqueous solutions of five amphiphiles
Author(s)
Troncoso, J; Zemankova, K; Jover, A
Year
2017
Is Peer Reviewed?
Yes
Journal
Journal of Molecular Liquids
ISSN:
0167-7322
Volume
241
Page Numbers
525-529
DOI
10.1016/j.molliq.2017.06.022
Web of Science Id
WOS:000407535000062
Abstract
Aqueous dilute solutions of 2-butoxyethanol, 1,2-hexanediol, tert-butanol, 1-pentylamine and 1-butylamine are analized through the dynamic light scattering technique. The mutual diffusion coefficient is determined against amphiphile composition, showing, in all cases, clear minima in the dilute region. Using the Stokes-Einstein relation, the mean size of the aggregates is also obtained as a function of mole fraction. For enough concentrated solutions, structures in the range 2-20 angstrom are observed. It is found that both their size and the minimum amphiphile mole fraction for which aggregation is observed are strongly correlated with the hydrophobic character of the amphiphile. (C) 2017 Elsevier B.V. All rights reserved.
Keywords
Water solutions; Amphiphiles; Dynamic light scattering; Aggregation; Hydrophobicity
Tags
OPPT
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1,2-Hexanediol
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