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HERO ID
4854486
Reference Type
Journal Article
Title
Solubilities of carbon dioxide in 2-methoxyethyl acetate, 1-methoxy-2-propyl acetate and 3-methoxybutyl acetate
Author(s)
Li, Yun; Zheng, D; Dong, Li; Xiong, Bin
Year
2014
Is Peer Reviewed?
1
Journal
Journal of Chemical Thermodynamics
ISSN:
0021-9614
Volume
74
Page Numbers
126-132
DOI
10.1016/j.jct.2014.01.019
Web of Science Id
WOS:000335904400016
Abstract
The solubilities of CO2 in 2-methoxyethyl acetate, 1-methoxy-2-propyl acetate, and 3-methoxybutyl acetate were measured by isothermal synthesis method under pressures up to 1.2 MPa and at temperatures ranging from (293.15 to 333.15) K. Henry's constant was calculated based on experimental data regression. The solubilities of CO2 were found to increase with decreased temperature and increased the methyl group to the molecular structure of the absorbent. Henry's constant and volumetric solubility of selected absorbents at T = 298.15 K were compared with those of commercial absorbents and common solvents. 3-Methoxybutyl acetate showed the best performance by mole fraction, and 2-methoxyethyl acetate behaved the best by volumetric fraction. Based on Henry's constant, thermodynamic properties such as Gibbs free energy of solution, enthalpy of solution, and absorption entropy of solution were determined. These properties are very essential for designing an absorption process. (C) 2014 Elsevier Ltd. All rights reserved.
Keywords
Solubilities of CO2; Henry's constant; Thermodynamic properties; Isothermal synthesis method
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OPPT
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3-Methoxybutyl acetate
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