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HERO ID
5024249
Reference Type
Journal Article
Title
Degradation of PFOA Substitute: GenX (HFPO-DA Ammonium Salt): Oxidation with UV/Persulfate or Reduction with UV/Sulfite?
Author(s)
Bao, Y; Deng, S; Jiang, X; Qu, Y; He, Y; Liu, L; Chai, Q; Mumtaz, M; Huang, J; Cagnetta, G; Yu, G
Year
2018
Is Peer Reviewed?
1
Journal
Environmental Science & Technology
ISSN:
0013-936X
EISSN:
1520-5851
Volume
52
Issue
20
Page Numbers
11728-11734
Language
English
PMID
30207460
DOI
10.1021/acs.est.8b02172
Web of Science Id
WOS:000447816100030
Abstract
Hexafluoropropylene oxide dimer acid (HFPO-DA, ammonium salt with trade name: GenX) has been recently detected in river water worldwide. There are significant concerns about its persistence, and potential adverse effects to the biota. In this study, the degradability of GenX by typical advanced redox technologies (UV/persulfate and UV/sulfate) is investigated. Results demonstrate that <5% GenX is oxidized after 3 h in UV/persulfate system, which is much lower than ∼27% for PFOA. In comparison, GenX can be readily degraded and defluorinated by hydrated electron (eaq-) generated by UV/sulfite system. Specifically, GenX is not detectable after 2 h, and >90% of fluoride ion is recovered 6 h later. This is attributed to the accumulation and subsequent degradation of CF3CF2COOH and CF3COOH, which are stable intermediates of GenX degradation. Mechanistic investigations suggest that the etheric bond in the molecule is a favorable attack point for the eaq-. Such finding is corroborated by quantum chemical calculations. The side CF3- at the α-carbon probably acts as an effective barrier that prevents GenX from being cleaved by SO4-• or OH• at its most sensible point (i.e. the carboxyl group). This study illustrates that reduction by UV/sulfite might be a promising technology to remove GenX from contaminated water.
Keywords
environmental studies; ultraviolet radiation; organic contaminants; water pollution; oxidation; degradation; reduction; fluoride; ammonium; quantum chemistry; carboxyl group; ammonium salts; chemical bonds; degradability; organic chemistry; intermediates; chemical attack; sulfate; sulfite
Tags
PFAS
•
Additional PFAS (formerly XAgency)
•
Expanded PFAS SEM (formerly PFAS 430)
Ammonium 4,8-dioxa-3H-perfluorononanoate
•
GenX Chemicals (CASRN 13252-13-6 and CASRN 62037-80-3)
LitSearch - GenX: July 2017 - Feb 2019
WoS
LitSearch GenX Ammonium Salt: Feb 2018 - Feb 2019
PubMed
WoS
•
PFAS 150
Literature Search Update December 2020
PubMed
Literature Search August 2019
PubMed
Not prioritized for screening
Ammonium perfluoro-2-methyl-3-oxahexanoate
Perfluoro-2-methyl-3-oxahexanoic acid
•
PFHxS
•
PFOA (335-67-1) and PFOS (1763-23-1)
Literature Search Update (2013-2019)
WOS
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