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5349167 
Journal Article 
Interactions between azines and alcohols: a rotational study of pyridine-tert-butyl alcohol 
Spada, L; Uriarte, I; Li, W; Evangelisti, L; Cocinero, EJ; Caminati, W 
2019 
1 
Physical Chemistry Chemical Physics
ISSN: 1463-9076
EISSN: 1463-9084 
21 
7 
3545-3549 
English 
30168540 
We assigned the rotational spectra of the parent and the OD isotopologues of the intermolecular complex pyridine-tert-butyl alcohol. The rotational and 14N quadrupole coupling constants are in agreement with a σ-type shape and a Cs symmetry of the complex. The two subunits are held together by a "classical" O-HN intermolecular hydrogen bond. Structural features of these hydrogen bonds are given and compared to those of similar molecular adducts. The ON distance decreases by 4 mÅ upon deuteration of the hydroxyl group, denoting a marked reverse Ubbelohde effect of the O-HN hydrogen bond. 
IRIS
• tert-Butanol
     Excluded/ Not on Topic
          Chemical Analysis/Fuel Chemistry
     LitSearch: Jan 2017 - July 2019
          PubMed