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6646768 
Journal Article 
Binary miscible blends of poly(methyl methacrylate)/poly(alpha-methyl styrene-co-acrylonitrile). III. Investigation of the phase behavior and morphology during shear flow 
Madbouly, SA; Ougizawa, T; , 
2002 
Yes 
Journal of Macromolecular Science: Part B - Physics
ISSN: 0022-2348 
MARCEL DEKKER INC 
NEW YORK 
B41 
3 
629-646 
WOS:000176590500013 
The phase behavior and morphology of poly(methyl methacrylate) (PMMA) and poly(alpha-methyl styrene-co-acrylonitrile) (PalphaMSAN) blends have been investigated under different shear rates using a simple shear apparatus and transmission electron microscopy (TEM), respectively. The lower critical solution temperature-type (LCST-type) phase diagram detected under quiescent condition was shifted a few degrees to higher temperatures with increasing shear flow, i.e., the shear could suppress the phase separation and enlarge the homogenous region. There was no sign detected for shear-induced demixing over a wide range of shear rates and temperatures for all the measuring compositions. The normalized shift in the cloud point DeltaT((gamma) over dot)/T(0) vs. shear rate ((gamma) over dot) for this blend was also investigated and compared with previous studies for high molecular weight polymer blends, oligomer mixtures, and polymer solutions as well as simple liquid mixtures. It was found that the characteristic relaxation time for concentration fluctuations is the most sensitive parameter, which controls the behavior of the mixtures under shear flow i.e., the larger the characteristic time for concentration fluctuations are, the larger the change in the cloud points under shear will be. The morphology of the critical blend composition (PalphaMSAN/PMMA = 25/75) was investigated as a function of shear rates at two different quenching temperatures (different quenching depth). At 189degreesC (17degreesC above the quiescent cloud point), the morphology of the blend was strongly elongated and oriented parallel to the flow direction and, shear-induced mixing was detected at a critical shear rate value (10 sec(-1)), at which no morphology was detected. At 193degreesC (21degreesC above the quiescent cloud point), the blend morphology showed a slightly elongated co-continuous two-phase structure with a significant decrease in the periodic distance; however, no shear-induced mixing could be detected at this temperature at shear rates up to 40 sec(-1).