Synthesis of dibenzo[b,f][1,4]oxazepin-11(10H)-ones from 2-nitrobenzoic acids
Samet, AV; Kislyi, KA; Marshalkin, VN; Semenov, VV; ,
| HERO ID | 7686424 |
|---|---|
| In Press | No |
| Year | 2006 |
| Title | Synthesis of dibenzo[b,f][1,4]oxazepin-11(10H)-ones from 2-nitrobenzoic acids |
| Authors | Samet, AV; Kislyi, KA; Marshalkin, VN; Semenov, VV; , |
| Journal | Russian Chemical Bulletin |
| Page Numbers | 549-553 |
| Abstract | Base-catalyzed intramolecular nucleophilic substitution for the 2-nitro group in 2-hydroxyanilides of 2-nitrobenzoic acids gave dibenzo[b,f][1,4]oxazepin-11(10H)-ones. In particular, 3 -nitrodibenzo[b,f][1,4] oxazepin-11 (10H)-one was obtained from N-(2-hydroxyphenyl)2,4-dinitrobenzamide. The nitro group in the product could also be replaced under the action of O- and S-nucleophiles. |
| Wosid | WOS:000239714700021 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |