Simultaneous extraction and analysis by high performance liquid chromatography coupled to diode array and mass spectrometric detectors of bixin and phenolic compounds from annatto seeds

Chisté, RC; Yamashita, F; Gozzo, FC; Mercadante, AZ

HERO ID

1054677

Reference Type

Journal Article

Year

2011

Language

English

PMID

21111424

HERO ID 1054677
In Press No
Year 2011
Title Simultaneous extraction and analysis by high performance liquid chromatography coupled to diode array and mass spectrometric detectors of bixin and phenolic compounds from annatto seeds
Authors Chisté, RC; Yamashita, F; Gozzo, FC; Mercadante, AZ
Journal Journal of Chromatography A
Volume 1218
Issue 1
Page Numbers 57-63
Abstract This study was designed to identify and quantify the carotenoids and phenolic compounds from annatto seeds using high performance liquid chromatography coupled to diode array and mass spectrometer detectors (HPLC-DAD-MS/MS). Furthermore, using response surface methodology, an optimized procedure for simultaneous extraction of these compounds was established. In addition to bixin, known to be the main carotenoid in annatto seeds, hypolaetin and a caffeoyl acid derivative were identified as the main phenolic compounds. The optimized procedure involved 15 extractions using acetone:methanol:water (50:40:10, v/v/v) as solvent, a solid-liquid ratio of 1:9 (m/v) and an extraction time of 5 min. Validation data indicated that the HPLC method proposed provided good linearity, sensitivity, procedure accuracy, system precision and suggested its suitability for the simultaneous analysis of phenolic compounds and carotenoids in annatto seeds.
Doi 10.1016/j.chroma.2010.10.094
Pmid 21111424
Is Certified Translation No
Dupe Override No
Comments Source: Web of Science 000286494100007
Is Public Yes
Language Text English
Keyword Bixa orellana L.; Carotenoids; Phenolic compounds; Response surface methodology; HPLC-DAD-MS/MS
Is Qa No