Dehalogenation of 1,3-diiodotricyclo[3.3.0.0(3,7)]octane: generation of 1,3-dehydrotricyclo[3.3.0.0(3,7)]octane, a 2,5-methano-bridged [2.2.1]propellane
Ayats, C; Camps, P; Fernández, JA; Vázquez, S
| HERO ID | 1071123 |
|---|---|
| In Press | No |
| Year | 2007 |
| Title | Dehalogenation of 1,3-diiodotricyclo[3.3.0.0(3,7)]octane: generation of 1,3-dehydrotricyclo[3.3.0.0(3,7)]octane, a 2,5-methano-bridged [2.2.1]propellane |
| Authors | Ayats, C; Camps, P; Fernández, JA; Vázquez, S |
| Journal | Chemistry: A European Journal |
| Volume | 13 |
| Issue | 5 |
| Page Numbers | 1522-1532 |
| Abstract | Compounds isolated from the reaction of (+/-)-1,3-diiodotricyclo[3.3.0.0(3,7)]octane with molten sodium or tBuLi suggest the intermediate formation of (+/-)-1,3-dehydrotricyclo[3.3.0.0(3,7)]octane. Worthy of note is the formation of stereoisomeric bi(5-methylenebicyclo[2.2.1]hept-2-ylidene) derivatives, probably by coupling of two units of (+/-)-1,3-dehydrotricyclo[3.3.0.0(3,7)]octane of the same or different absolute configuration followed by fragmentation, processes that have been studied by theoretical calculations. |
| Doi | 10.1002/chem.200600859 |
| Pmid | 17091516 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Language Text | English |
| Is Qa | No |