Metabolite detection as evidence for naturally occurring aerobic PCB biodegradation in Hudson River sediments

Flanagan, WP; May, RJ

HERO ID

1749017

Reference Type

Journal Article

Year

1993

Language

English

HERO ID 1749017
In Press No
Year 1993
Title Metabolite detection as evidence for naturally occurring aerobic PCB biodegradation in Hudson River sediments
Authors Flanagan, WP; May, RJ
Journal Environmental Science & Technology
Volume 27
Issue 10
Page Numbers 2207-2212
Abstract BIOSIS COPYRIGHT: BIOL ABS. Although aerobic microbial biodegradation of polychlorinated biphenyls (PCBs) has been widely demonstrated in the laboratory, there is little direct evidence that this process occurs naturally in the environment. A clear indicator of naturally occurring aerobic PCB biodegradation would be the presence of intermediate metabolites such as chlorobenzoic acids (CBAs) in contaminated sediments. CBAs have been detected in contaminated sediment cores, and their concentration profiles were correlated with PCB depth profiles. From the congener distribution pattern of the CBAs detected, it is extremely unlikely that these compounds were derived from either the breakdown of chlorinated herbicides or the carboxylation of phenols. No CBAs were detected in sediment samples not contaminated with PCBs. In addition, other metabolites which are less prone to source ambiguity, including 2,3-dihydro-2,3-dihydroxy-2'-chlorobiphenyl and 2,3-dihydroxy-2'-chlorobiphenyl, have also been detecte
Wosid WOS:A1993LZ74900037
Is Certified Translation No
Dupe Override No
Is Public Yes
Language Text English
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