Communication: Two measures of isochronal superposition
Roed, LA; Gundermann, D; Dyre, JC; Niss, K
HERO ID
2219819
Reference Type
Journal Article
Year
2013
Language
English
PMID
| HERO ID | 2219819 |
|---|---|
| In Press | No |
| Year | 2013 |
| Title | Communication: Two measures of isochronal superposition |
| Authors | Roed, LA; Gundermann, D; Dyre, JC; Niss, K |
| Journal | Journal of Chemical Physics |
| Volume | 139 |
| Issue | 10 |
| Page Numbers | 101101 |
| Abstract | A liquid obeys isochronal superposition if its dynamics is invariant along the isochrones in the thermodynamic phase diagram (the curves of constant relaxation time). This paper introduces two quantitative measures of isochronal superposition. The measures are used to test the following six liquids for isochronal superposition: 1,2,6 hexanetriol, glycerol, polyphenyl ether, diethyl phthalate, tetramethyl tetraphenyl trisiloxane, and dibutyl phthalate. The latter four van der Waals liquids obey isochronal superposition to a higher degree than the two hydrogen-bonded liquids. This is a prediction of the isomorph theory, and it confirms findings by other groups. |
| Doi | 10.1063/1.4821163 |
| Pmid | 24050319 |
| Wosid | WOS:000324387400001 |
| Is Certified Translation | No |
| Dupe Override | No |
| Comments | Scopus URL: https://www.scopus.com/inward/record.uri?eid=2-s2.0-84903362089&doi=10.1063%2f1.4821163&partnerID=40&md5=5b997b9301cf0fc61af7c7de5fe31a9c |
| Is Public | Yes |
| Language Text | English |
| Is Peer Review | Yes |