Environmental fate of RDX and TNT

Sikka, HC; Bannerjee, S; Pack, EJ; Appleton, HT

HERO ID

2342481

Reference Type

Technical Report

Year

1980

HERO ID 2342481
Year 1980
Title Environmental fate of RDX and TNT
Authors Sikka, HC; Bannerjee, S; Pack, EJ; Appleton, HT
Publisher Text U.S. Army Medical Research and Materiel Command
City Fort Detrick, MD
Page Numbers 1-142
Abstract The role of a number of processes (photodegradation, hydrolysis, biodegradation, and sorption to sediment) which may affect the environmental fate of RDX was examined under laboratory conditions. Photodegradation of RDX appears to be a fairly rapid process (half-life of 9-13 hours) and one ofthe intermediate photolysis product may be a nitrosamine. RDX does not hydrolyze in an aqueous solution at a pH range normally formed in natural waters. RDX does not sorb significantly to the sediment. Following a lag period of 2:3 weeks, biodegradation of RDX (half-life about 7 days) occurs in Holston River water supplemented with sediment. Sorption of TNT to sediment is relatively low after 24 hours. TNT degrades in the presence of sediment and the products of degradation appear to bind strongly to sediment with time.
Report Number TR 81-538
Is Certified Translation No
Dupe Override No
Comments Corporate author: Syracuse Research Corporation; Contract No. DAMD17-77-C-7026
Is Public Yes