Highly active and green mesostructured titanosilicate catalysts synthesized for selective synthesis of benzoquinones
Selvaraj, M
| HERO ID | 2896694 |
|---|---|
| In Press | No |
| Year | 2014 |
| Title | Highly active and green mesostructured titanosilicate catalysts synthesized for selective synthesis of benzoquinones |
| Authors | Selvaraj, M |
| Volume | 4 |
| Issue | 8 |
| Page Numbers | 2674-2684 |
| Abstract | Two-dimensional hexagonal thick-walled mesoporous titanosilicate catalysts synthesized using various amounts of titanium were used for the synthesis of 2,3,5-trimethyl-1,4-benzoquinone (TMB=O) by liquid-phase oxidation of 2,3,6-trimethylphenol (TMP-OH). These catalysts were also used for the oxidation of di-/tri-substituted phenols to produce 2,6-disubstituted p-benzoquinones (DSBQs). A promising chemical treatment method, for the preparation of green mesoporous TiSBA-15(6) or Washed TiSBA-15(6), was used for removal of non-framework TiO2 nanoparticle species from the active surface, and the catalytic activity of the recovered mesoporous TiSBA-15(6) catalyst has been evaluated. To confirm the green aspects, recyclability and hot-catalytic filtration experiments were performed. Based on the experimental results, it was found that the green mesoporous TiSBA-15(6) is a highly active, recyclable, and promising heterogeneous catalyst for the selective synthesis of TMB=O and DSBQs and produces >99% TMB=O selectivity with 100% TMP-OH conversion at 353 K for 60 min and 90-100% DSBQs selectivity with 83-99% phenol conversion at 330 K for 1-5 h. |
| Doi | 10.1039/c4cy00313f |
| Wosid | WOS:000339551400051 |
| Is Certified Translation | No |
| Dupe Override | No |
| Comments | Journal:CATALYSIS SCIENCE & TECHNOLOGY 2044-4753 |
| Is Public | Yes |