Chlorination of (Phebox)Ir(mesityl)(OAc) by Thionyl Chloride
Zhou, M; Goldman, AS
HERO ID
2902047
Reference Type
Journal Article
Year
2015
Language
English
PMID
| HERO ID | 2902047 |
|---|---|
| In Press | No |
| Year | 2015 |
| Title | Chlorination of (Phebox)Ir(mesityl)(OAc) by Thionyl Chloride |
| Authors | Zhou, M; Goldman, AS |
| Journal | Molecules |
| Volume | 20 |
| Issue | 6 |
| Page Numbers | 10122-10130 |
| Abstract | Pincer (Phebox)Ir(mesityl)(OAc) (2) (Phebox = 3,5-dimethylphenyl-2,6-bis(oxazolinyl)) complex, formed by benzylic C-H activation of mesitylene (1,3,5-trimethylbenzene) using (Phebox)Ir(OAc)2OH2 (1), was treated with thionyl chloride to rapidly form 1-(chloromethyl)-3,5-dimethylbenzene in 50% yield at 23 °C. A green species was obtained at the end of reaction, which decomposed during flash column chromatography to form (Phebox)IrCl2OH2 in 87% yield. |
| Doi | 10.3390/molecules200610122 |
| Pmid | 26039335 |
| Wosid | WOS:000357992700040 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Language Text | English |
| Keyword | chlorination; phebox ligand; iridium mesityl; thionyl chloride; pincer complex |