Highly enantioselective Michael addition reactions with new trimeric chiral phase transfer catalysts

Beneto, AJ; Sivamani, J; Ashokkumar, V; Balasaravanan, R; Duraimurugan, K; Siva, A

HERO ID

2904592

Reference Type

Journal Article

Year

2015

HERO ID 2904592
In Press No
Year 2015
Title Highly enantioselective Michael addition reactions with new trimeric chiral phase transfer catalysts
Authors Beneto, AJ; Sivamani, J; Ashokkumar, V; Balasaravanan, R; Duraimurugan, K; Siva, A
Journal New Journal of Chemistry
Volume 39
Issue 4
Page Numbers 3098-3104
Abstract New types of mesitylene based tri-site containing asymmetric quaternary ammonium salts 9a and 9b have been prepared and used as efficient chiral phase transfer catalysts for enantioselective Michael addition reactions between the chalcones and diethylmalonate under mild reaction conditions such as lower concentration of base, catalyst and ultrasonic conditions with very good chemical yields (up to 98%) and ee's (up to 99%).
Doi 10.1039/c4nj02395a
Wosid WOS:000352543800093
Is Certified Translation No
Dupe Override No
Is Public Yes