Synthesis of Photoswitchable Magnetic Au-Fullerosome Hybrid Nanomaterials for Permittivity Enhancement Applications

Wang, M; Jeon, S; Su, C; Yu, T; Tan, LS; Chiang, LY

HERO ID

3044667

Reference Type

Journal Article

Year

2015

Language

English

PMID

26287136

HERO ID 3044667
In Press No
Year 2015
Title Synthesis of Photoswitchable Magnetic Au-Fullerosome Hybrid Nanomaterials for Permittivity Enhancement Applications
Authors Wang, M; Jeon, S; Su, C; Yu, T; Tan, LS; Chiang, LY
Journal Molecules
Volume 20
Issue 8
Page Numbers 14746-14760
Abstract We designed and synthesized several nanomaterials 3 of three-layered core-shell (γ-FeOx@AuNP)@[C60(>DPAF-C9) 1 or 2]n nanoparticles (NPs). These NPs having e(-)-polarizable fullerosome structures located at the outer layer were fabricated from highly magnetic core-shell γ-FeOx@AuNPs. Fullerosomic polarization of 3 was found to be capable of causing a large amplification of material permittivity that is also associated with the photoswitching effect in the frequency range of 0.5-4.0 GHz. Multilayered synthetic construction allows Förster resonance energy transfer (FRET) of photoinduced accumulative surface plasmon resonance (SPR) energy in the gold layer to the partially bilayered C60(>DPAF-C9) 1 or 2-derived fullerosome membrane shell layer in a near-field of direct contact without producing radiation heat, which is commonly associated with SPR.
Doi 10.3390/molecules200814746
Pmid 26287136
Is Certified Translation No
Dupe Override No
Is Public Yes
Language Text English