Amphiphilic perylenetretracarboxyl diimide dimer and its application in field effect transistor

Wang, Y; Chen, Y; Li, R; Wang, S; Su, W; Ma, P; Wasielewski, MR; Li, X; Jiang, J

HERO ID

3559672

Reference Type

Journal Article

Year

2007

Language

English

PMID

17408297

HERO ID 3559672
In Press No
Year 2007
Title Amphiphilic perylenetretracarboxyl diimide dimer and its application in field effect transistor
Authors Wang, Y; Chen, Y; Li, R; Wang, S; Su, W; Ma, P; Wasielewski, MR; Li, X; Jiang, J
Journal Langmuir
Volume 23
Issue 10
Page Numbers 5836-5842
Abstract A novel perylene diimide (PDI) derivative with typical amphiphilic character, 2, was designed and prepared. The spectroscopic studies on this compound in solution revealed the face-to-face dimeric configuration and effective pi-pi interaction between the two perylene rings. This amphiphilic PDI derivative was fabricated into highly ordered films by Langmuir-Blodgett (LB) technique and fabricated into an organic field effect transistor (OFET), which shows carrier mobility around 0.05 cm(2) V(-1) s(-1) and current modulation of 10(3). This OFET performance is much better than that of monomeric PDI 1 and can be attributed to the unique face-to-face structure of 2, which promotes the interactions between neighboring PDI ring in LB film as indicated by the pi-A isotherms and UV-vis absorption.
Doi 10.1021/la063729f
Pmid 17408297
Wosid WOS:000246071800091
Is Certified Translation No
Dupe Override No
Is Public Yes
Language Text English