A new visible light bimolecular photoinitiator system for free radical polymerization
Chen, Y; Li, G; Han, J; Wang, T
| HERO ID | 3625221 |
|---|---|
| In Press | No |
| Year | 2011 |
| Title | A new visible light bimolecular photoinitiator system for free radical polymerization |
| Authors | Chen, Y; Li, G; Han, J; Wang, T |
| Journal | Journal of Photochemistry and Photobiology A: Chemistry |
| Volume | 222 |
| Issue | 2-3 |
| Page Numbers | 330-335 |
| Abstract | Abstract: A new bimolecular photoinitiator system consisting of a ferrocenium salt (Fc) and N-methyl-2-pyrrolidone (NMP) is developed for free radical photopolymerization under visible light irradiation, which was delivered by a halogen lamp. Photopolymerization profiles of tripropylene glycol diacrylate (TPGDA) show that high conversion can be easily achieved. The processes associated with the Fc/NMP system are investigated by photochemical and electrochemical experiments. The results show that the photoinitiation mechanism of this bimolecular system could occur through charge transfers between Fc and NMP. ds: Internet resource her supplied data e field[29]: NMP |
| Doi | 10.1016/j.jphotochem.2011.07.005 |
| Wosid | WOS:000295754000004 |
| Is Certified Translation | No |
| Dupe Override | No |
| Comments | Journal: ISSN: |
| Is Public | Yes |
| Keyword | Photopolymerization; Photochemistry; Ferrocenium salt; N-methyl-2-pyrrolidone; Photoinitiator |