Organometallic Lewis Acids, Part LIX[1] Pentacarbonylrhenium Complexes with Phosphorus Tricyanide and Dicyanophosphide
Sacher, W; Schmidpeter, A; Beck, W
| HERO ID | 3860743 |
|---|---|
| In Press | No |
| Year | 2015 |
| Title | Organometallic Lewis Acids, Part LIX[1] Pentacarbonylrhenium Complexes with Phosphorus Tricyanide and Dicyanophosphide |
| Authors | Sacher, W; Schmidpeter, A; Beck, W |
| Journal | Zeitschrift fuer Anorganische und Allgemeine Chemie |
| Volume | 641 |
| Issue | 5 |
| Page Numbers | 762-764 |
| Abstract | The addition of Re(CO)(5)(+) [as Re(CO)(5)FBF3] to P(CN)(3) and to P(CN)(2)(-) affords the complexes [Ro(CO)(5)](3)P(CN)(3)(BE4)(3) and Re(CO)(5)P(CN)(2), respectively. The spectroscopic data indicate that Re(CO)(5)(+) is coordinated to each of the three cyano groups of P(CN)(3) to give {P[C equivalent to N-Re(CO)(5)](3)}[BF4](3), whereas the psoudohalido P(CN)(2)(-) is bonded to the rhenium cation through the phosphorus atom. |
| Doi | 10.1002/zaac.201500068 |
| Wosid | WOS:000353034600002 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Keyword | Pentacarbonyirhenium; Phosphorus tricyanide; Dicyanophosphide |