Assessing uncertainty in annual nitrogen, phosphorus, and suspended sediment load estimates in three agricultural streams using a 21-year dataset

Kelly, PT; Vanni, MJ; Renwick, WH

HERO ID

4561614

Reference Type

Journal Article

Year

2018

Language

English

PMID

29354871

HERO ID 4561614
In Press No
Year 2018
Title Assessing uncertainty in annual nitrogen, phosphorus, and suspended sediment load estimates in three agricultural streams using a 21-year dataset
Authors Kelly, PT; Vanni, MJ; Renwick, WH
Journal Environmental Monitoring and Assessment
Volume 190
Issue 2
Page Numbers 91
Abstract Accurate estimation of constituent loads is important for studies of ecosystem mass balance or total maximum daily loads. In response, there has been an effort to develop methods to increase both accuracy and precision of constituent load estimates. The relationship between constituent concentration and stream discharge is often complicated, potentially leading to high uncertainty in load estimates for certain constituents, especially at longer-term (annual) scales. We used the loadflex R package to compare uncertainty in annual load estimates from concentration vs. discharge relationships in constituents of interest in agricultural systems, including ammonium as nitrogen (NH4-N), nitrate as nitrogen (NO3-N), soluble reactive phosphorus (SRP), and suspended sediments (SS). We predicted that uncertainty would be greatest in NO3-N and SS due to complex relationships between constituent concentration and discharge. We also predicted lower uncertainty with a composite method compared to regression or interpolation methods. Contrary to predictions, we observed the lowest uncertainty in annual NO3-N load estimates (relative error 1.5-23%); however, uncertainty was greatest in SS load estimates, consistent with predictions (relative error 19-96%). For all constituents, we also generally observed reductions in uncertainty by up to 34% using the composite method compared to regression and interpolation approaches, as predicted. These results highlight differences in uncertainty among different constituents and will aid in model selection for future studies requiring accurate and precise estimates of constituent load.
Doi 10.1007/s10661-018-6470-4
Pmid 29354871
Wosid WOS:000424113700037
Is Certified Translation No
Dupe Override No
Is Public Yes
Language Text English