Studies on Lewis acid-mediated intramolecular cyclization reactions of allene-ene systems
Hiroi, K; Watanabe, T; Tsukui, A
| HERO ID | 4923711 |
|---|---|
| In Press | No |
| Year | 2000 |
| Title | Studies on Lewis acid-mediated intramolecular cyclization reactions of allene-ene systems |
| Authors | Hiroi, K; Watanabe, T; Tsukui, A |
| Journal | Chemical and Pharmaceutical Bulletin |
| Volume | 48 |
| Issue | 3 |
| Page Numbers | 405-409 |
| Abstract | The Lewis acid-mediated reactions of allene-ene compounds, derived from 3-methylcitronellal or dimethyl malonate, were carried out using various Lewis acids such as ethylaluminum dichloride, diethylaluminum chloride, titanium chloride, zinc chloride etherate, or boron trifluoride etherate, affording unexpectedly intramolecular [2+2]cycloaddition products under some particular reaction conditions without any formation of intramolecular ene reaction products. |
| Doi | 10.1248/cpb.48.405 |
| Pmid | 10726866 |
| Wosid | WOS:000085699500018 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Language Text | English |
| Keyword | allene; [2+2]cycloaddition; Lewis acid; allene-ene system; intramolecular cycloaddition |