Retention index monitoring of compounds of chemical defense interest using thermal desorption gas chromatography

Hancock, JR; Peters, GR

HERO ID

4931453

Reference Type

Journal Article

Year

1991

Language

English

HERO ID 4931453
In Press No
Year 1991
Title Retention index monitoring of compounds of chemical defense interest using thermal desorption gas chromatography
Authors Hancock, JR; Peters, GR
Journal Journal of Chromatography
Volume 538
Issue 2
Page Numbers 249-258
Abstract BIOSIS COPYRIGHT: BIOL ABS. Retention index monitoring using thermal desorption gas chromatographic analysis was developed as a method for the verification of compounds of chemical defense interest in environmental matrices. Gas chromatography retention indices were determined by loading solid adsorbent packed sampling tubes initially with the target compounds and subsequently with a series of n-alkaline probes. The resulting chromatographic performance and gas chromatography retention indices were shown to be independent of the tube loading method. A database of gas chromatography retention indices for chemical warfare agents and simulants was compiled and, in conjunction with simultaneous flame ionizatin and flame photometric detection, applied to the identification of triethyl phosphate, tributyl phosphate and diethyl malonate in water and soil samples.
Doi 10.1016/S0021-9673(01)88845-2
Wosid WOS:A1991EY98500003
Is Certified Translation No
Dupe Override No
Is Public Yes
Language Text English