Glycerol Esters from the Reaction of Glycerol with Dicarboxylic Acid Esters
Cho, GHP; Yeong, SK; Ooi, TL; Chuah, CH
| HERO ID | 4933604 |
|---|---|
| In Press | No |
| Year | 2006 |
| Title | Glycerol Esters from the Reaction of Glycerol with Dicarboxylic Acid Esters |
| Authors | Cho, GHP; Yeong, SK; Ooi, TL; Chuah, CH |
| Journal | Journal of Surfactants and Detergents |
| Volume | 9 |
| Issue | 2 (Second Quarter 2006) |
| Page Numbers | 147-152 |
| Abstract | Mono- and di-esterified glycerols were synthesized by the base catalyzed reaction of glycerol with aliphatic dicarboxylic acid esters (C^sub 2^-C^sub 9^): 2,3-dihydroxy-propyl oxalate (2), 1,3 dioxalyloxy propan-2-ol (3), 1,3-dimethoxyoxalyloxy propan2-ol (5), 2,3-dihydroxy-propyl malonate (6), 2,3-dihydroxy-propyl methyl malonate (7), 2,3-dihydroxy-propyl methyl succinate (8), 1,3-dimethoxysuccinyloxy propan-2-ol (9), 2,3-dihydroxy-propyl methyl glutarate (10), 1,3-dimethoxyglutaryloxy propan-2-ol (11), 2,3-dihydroxy-propyl methyl azelate (14), and 1,3-dimethoxyazelyloxy propan-2-ol (15). Their structures were elucidated by spectrometric methods. Compounds 8, 10, 2,3-dihydroxy-propl methyl adipate (12) and 14 were found to possess surface active properties and the ability to reduce the interfacial tension between paraffin and water. [PUBLICATION ABSTRACT] |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Keyword | Surfactants; Organic chemicals; Organic chemistry; Spectrum analysis |