Capillary GC determination of short-chain dicarboxylic acids in rain, fog, and mist

Kawamura, K; Steinberg, S; Kaplan, IR

HERO ID

4933633

Reference Type

Journal Article

Year

1985

HERO ID 4933633
In Press No
Year 1985
Title Capillary GC determination of short-chain dicarboxylic acids in rain, fog, and mist
Authors Kawamura, K; Steinberg, S; Kaplan, IR
Journal International Journal of Environmental Analytical Chemistry
Volume 19
Issue 3 (1985)
Page Numbers 175-188
Abstract A capillary GC and GC-MS method, employing dibutyl esters is described for determining short-chain dicarboxylic acids in rain, fog and mist samples collected in the Los Angeles area. Approximately twenty dicarboxylic acids (C sub(2)-C sub(10)) were identified in the water samples, including cis (maleic) and trans (fumaric) unsaturated, saturated, normal, branched and aromatic. Oxalic acid is the dominant acid, followed by succinic and malonic acids. The total concentrations measured are 2.9-51 mu M, 64-66 mu M and 12 mu M for rain, fog and mist samples, respectively. These diacids are probably produced by photooxidation of anthropogenic and possibly biogenic organic compounds in the atmosphere.
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Dupe Override No
Is Public Yes
Keyword rain; fog; gas chromatography; water quality; chemical analysis