Properties of endohedral N@C-60
Pietzak, B; Waiblinger, M; Murphy, TA; Weidinger, A; Hohne, M; Dietel, E; Hirsch, A
| HERO ID | 4935958 |
|---|---|
| Year | 1998 |
| Title | Properties of endohedral N@C-60 |
| Book Title | EUROPEAN MATERIALS RESEARCH SOCIETY SYMPOSIA-PROCEEDINGS |
| Authors | Pietzak, B; Waiblinger, M; Murphy, TA; Weidinger, A; Hohne, M; Dietel, E; Hirsch, A |
| Volume | 68 |
| Page Numbers | 613-615 |
| Abstract | Endohedral N@C-60 (atomic nitrogen inside C-60) is produced by ion implantation. N@C-60 is soluble in organic solvents and stable in air. A special Feature is that it gives a very clear hyperfine split EPR signal with sharp lines even in the solid. This makes it an ideal probe for monitoring chemical reactions of C-60 via changes of the EPR signal. As an example, the formation of the monoadduct of diethyl malonate on C-60 will be discussed. In general, N@C-60 can be used as a probe or tracer for monitoring reactions or the transport of C-60. We show that C-60 is an ideal trap for atomic nitrogen. Nitrogen is in the center of C-60 and keeps its atomic structure. In a first experiment, the Vibrations of nitrogen in C-60 were studied. (C) 1998 Elsevier Science Ltd. All rights reserved. |
| Doi | 10.1016/S0008-6223(98)00038-4 |
| Wosid | WOS:000079731900028 |
| Is Certified Translation | No |
| Dupe Override | No |
| Comments | Journal:FULLERENES AND CARBON BASED MATERIALS |
| Is Public | Yes |
| Keyword | fullerenes; electron paramagnetic resonance (EPR) |