ELECTROCHEMICAL OXIDATION OF MALONIC ESTER AND ITS DERIVATIVES IN THE PRESENCE OF HALIDES AS MEDIATORS
Elinson, MN; Fedukovich, SK; Lizunova, TL; Nikishin, GI
| HERO ID | 4935998 |
|---|---|
| In Press | No |
| Year | 1992 |
| Title | ELECTROCHEMICAL OXIDATION OF MALONIC ESTER AND ITS DERIVATIVES IN THE PRESENCE OF HALIDES AS MEDIATORS |
| Authors | Elinson, MN; Fedukovich, SK; Lizunova, TL; Nikishin, GI |
| Journal | Soviet Electrochemistry |
| Volume | 28 |
| Issue | 4 |
| Page Numbers | 464-475 |
| Abstract | Esters of 1,1,2,2-ethanetetracarboxylic acid or of ethylenetetracarboxylic acid were obtained by electrochemical oxidation of malonic esters in the presence of halides as mediators. Esters of 1,1,2,2,3,3-propanehexacarboxylic acid or of cyclopropanehexacarboxylic acid were obtained by electrolysis in the presence of alkali metal bromides. An analogous process was used fir electrochemical ring closure of substituted 1,1,3,3-propanetetracarboxcylic acid esters to substituted 1,1,2,2-cyclopropanetetracarboxylic acid esters and for the assembly of four and five-membered rings from the corresponding esters of alpha,alpha,omega,omega-alkanetetracarboxylic acids. Common features and differences between the electrolysis of malonic esters and the esters of beta-oxoalkanecarboxcylic acids, 1,3-diketones, and malononitrile were studied under the conditions of mediated electrooxidation in the presence of halides. |
| Wosid | WOS:A1992KB28400013 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |