Palladium(II) aminoiminophosphoranate complexes as cross-coupling catalysts

Peganova, TA; Kalsin, AM; Ustynyuk, NA; Vasil'ev, AA

HERO ID

4936002

Reference Type

Journal Article

Year

2014

HERO ID 4936002
In Press No
Year 2014
Title Palladium(II) aminoiminophosphoranate complexes as cross-coupling catalysts
Authors Peganova, TA; Kalsin, AM; Ustynyuk, NA; Vasil'ev, AA
Journal Russian Chemical Bulletin
Volume 63
Issue 10
Page Numbers 2305-2308
Abstract The Tsuji-Trost reaction between diethyl malonate and allyl acetate catalyzed by palladium(II) NPN-aminoiminophosphoranate complexes yields mono- and diallylation products in the ratios depending on the complex used. The Suzuki-Miyaura cross-coupling of 4-bromoacetophenone with phenylboronic acid catalyzed by these palladium complexes proceeds with 66-99.5% conversions.
Doi 10.1007/s11172-014-0739-8
Wosid WOS:000356049900014
Is Certified Translation No
Dupe Override No
Is Public Yes
Keyword palladium(II) aminoiminophosphoranate complexes; cross-coupling catalysts; Tsuji-Trost reaction; Suzuki cross-coupling