Electrochemical oxidation of malonic esters in acetonitrile in the presence of iodides as mediators
Fedukovich, SK; Elinson, MN; Nikishin, GI
| HERO ID | 4936013 |
|---|---|
| In Press | No |
| Year | 1997 |
| Title | Electrochemical oxidation of malonic esters in acetonitrile in the presence of iodides as mediators |
| Authors | Fedukovich, SK; Elinson, MN; Nikishin, GI |
| Journal | Russian Chemical Bulletin |
| Volume | 46 |
| Issue | 3 |
| Page Numbers | 599-602 |
| Abstract | Electrochemical oxidation of malonic esters in acetonitrile in the presence of iodides follows two different pathways depending on the nature of the cation. In the presence of LiI, alkyl 1,1,2,2,3,3-propanetetracarboxylates were obtained in 85-98% yields. In the presence of Nat, KI, or Bu4NI, the formation of 1,1,2,2-ethanetetracarboxylates and their subsequent dehydrogenation to ethenetetracarboxylates was the main reaction pathway. |
| Doi | 10.1007/BF02495426 |
| Wosid | WOS:A1997XM64800043 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Keyword | electrochemical oxidation; malonic ester; mediators; esters of polycarboxylic acids |