Conjugate addition of thiols and malonates to thiocinnamates under PTC conditions
Marzorati, L; de Mattos, MC; Wladislaw, B; Di Vitta, C
| HERO ID | 4936051 |
|---|---|
| In Press | No |
| Year | 2002 |
| Title | Conjugate addition of thiols and malonates to thiocinnamates under PTC conditions |
| Authors | Marzorati, L; de Mattos, MC; Wladislaw, B; Di Vitta, C |
| Journal | Synthetic Communications |
| Volume | 32 |
| Issue | 9 |
| Page Numbers | 1427-1435 |
| Abstract | Addition of thiols or diethylmalonate to thiocinnamate, under solid-liquid PTC conditions, afforded the corresponding 1,4-adducts in moderate to good yields. A 2-pyrrolidinone was obtained using diethyl N-acetamidomalonate as Michael donor, via intramolecular cyclization of the parent adduct. |
| Doi | 10.1081/SCC-120003641 |
| Wosid | WOS:000175809600018 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Keyword | thiocinnamates; conjugate addition; phase transfer catalysis; pyrrolidinone |