Asymmetric Tsuji-Trost substitution in 3-acetoxy-1,3-diphenylpropene under phase-transfer conditions
Vasil'ev, AA; Lyubimov, SE; Serebryakov, EP; Davankov, VA; Zlotin, SG
| HERO ID | 4936169 |
|---|---|
| In Press | No |
| Year | 2012 |
| Title | Asymmetric Tsuji-Trost substitution in 3-acetoxy-1,3-diphenylpropene under phase-transfer conditions |
| Authors | Vasil'ev, AA; Lyubimov, SE; Serebryakov, EP; Davankov, VA; Zlotin, SG |
| Journal | Mendeleev Communications |
| Volume | 22 |
| Issue | 1 |
| Page Numbers | 39-40 |
| Abstract | P*-Chiral diamidophosphite ligand-assisted Pd-catalyzed Tsuji-Trost reaction between dimethyl malonate and prochiral 3-acetoxy-1,3-diphenylpropene in organic solvents using potassium carbonate as the base affords the substitution product in quantitative yields and with enantioselectivities up to 99% ee. |
| Doi | 10.1016/j.mencom.2012.01.015 |
| Wosid | WOS:000301020400015 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |