HYDROGENOLYSIS OF METHYL OLEATE OVER OXIDE CATALYST DERIVED FROM HYDROGEN STORAGE ALLOY
Chikamatsu, N; Tagawa, T; Goto, S
| HERO ID | 4936650 |
|---|---|
| In Press | No |
| Year | 1991 |
| Title | HYDROGENOLYSIS OF METHYL OLEATE OVER OXIDE CATALYST DERIVED FROM HYDROGEN STORAGE ALLOY |
| Authors | Chikamatsu, N; Tagawa, T; Goto, S |
| Journal | Journal of Chemical Engineering of Japan |
| Volume | 24 |
| Issue | 5 |
| Page Numbers | 604-609 |
| Abstract | A mixed oxide catalyst was prepared from a binary hyrdrogen storage alloy, Mg2Cu, and its activity and selectivity were compared with those of conventional CuCrO catalyst. The catalyst's activity was stable for the synthesis of C18 alcohol by gas-phase hydrogenolysis of methyl oleate in a continuous-flow reactor at 553 K under atmospheric pressure. Considerable amounts of unsaturated alcohol were produced together with saturated alcohol. From a kinetic study the rate equation was formulated for each alcohol. From XRD analysis, active sites are thought to be copper species on MgO support. |
| Doi | 10.1252/jcej.24.604 |
| Wosid | WOS:A1991GM17000010 |
| Is Certified Translation | No |
| Dupe Override | 4936650 |
| Is Public | Yes |
| Keyword | CHEMICAL REACTION; HYDROGENOLYSIS; METHYL OLEATE; KINETICS; CATALYST; UNSATURATED ALCOHOL |