MECHANISTIC INVESTIGATION OF OXIDATION OF GLUCOSE AND FRUCTOSE BY N-CHLORONICOTINAMIDE (NCN)
Pushpalatha, L
| HERO ID | 4947170 |
|---|---|
| In Press | No |
| Year | 2014 |
| Title | MECHANISTIC INVESTIGATION OF OXIDATION OF GLUCOSE AND FRUCTOSE BY N-CHLORONICOTINAMIDE (NCN) |
| Authors | Pushpalatha, L |
| Journal | Oxidation Communications |
| Volume | 37 |
| Issue | 1 |
| Page Numbers | 121-128 |
| Abstract | Kinetic investigation of oxidation of glucose and fructose, by alkaline solution of N-chloronicotinamide (NCN) has been carried out in the temperature range 308-328 K. The reaction shows first order in [alkali] and [substrate] and zero order in oxidant. Addition of nicotinamide (NA) has no effect. Increase in ionic strength of the medium does not change the rate. Effect of temperature on the rate of oxidation has been followed to show the validity of the Arrhenius equation and various activation parameters have been computed. The stoichiometry of the reaction was found to be 1:1. 1,2-enediol is found to be the reactive intermediate. Gluconic acid and formic acid are the products of oxidation for glucose and fructose, respectively. |
| Wosid | WOS:000336189500013 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Keyword | N-chloronicotinamide; glucose; fructose; mechanism; oxidation |