OXIDATION OF 2-ACETAMIDO-2-DEOXY-D-GLUCOSE BY CR-VI IN PERCHLORIC-ACID
Sala, LF; Palopoli, C; Signorella, S
| HERO ID | 4947455 |
|---|---|
| In Press | No |
| Year | 1995 |
| Title | OXIDATION OF 2-ACETAMIDO-2-DEOXY-D-GLUCOSE BY CR-VI IN PERCHLORIC-ACID |
| Authors | Sala, LF; Palopoli, C; Signorella, S |
| Journal | Polyhedron |
| Volume | 14 |
| Issue | 13-14 |
| Page Numbers | 1725-1730 |
| Abstract | The oxidation of 2-acetamido-2-deoxy-D-glucose by Cr-VI in perchloric acid has been found to follow the rate law: -d[Cr-VI]dt = (a+b[H+](2)+c[GlcNAc](2)[H+](2)) [Cr-VI](T) where a = 7.37 +/- 0.35 x 10(-5) s(-1); b = 3.90 +/- 0.67 x 10(-4) M(-2) s(-1); and c = 1.18 +/- 0.01 x 10(-3) M(-4) s(-1). This rate law corresponds to the reaction leading to the formation of 2-acetamido-2-deoxy-D-gluconic acid when a 20-fold or higher excess of aldose over chromium is employed. The results are discussed in terms of a possible mechanism with the associated reaction kinetics. |
| Doi | 10.1016/0277-5387(94)00467-S |
| Wosid | WOS:A1995RJ45500003 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |