Carbon black adsorbates: separation and identification of a carcinogen and some oxygenated polyaromatics

Gold, A

HERO ID

59863

Reference Type

Journal Article

Year

1975

Language

English

HERO ID 59863
In Press No
Year 1975
Title Carbon black adsorbates: separation and identification of a carcinogen and some oxygenated polyaromatics
Authors Gold, A
Journal Analytical Chemistry
Volume 47
Issue 8
Page Numbers 1469-1472
Abstract HEEP COPYRIGHT: BIOL ABS. A systematic effort was made to identify components in the neutral polar fraction of carbon black extract as well as the constituents of the polycyclic aromatic hydrocarbon fraction. One aromatic hydrocarbon in environmental samples whose structure has not been elucidated is cyclopenta(cd)pyrene. The method employed to deduce its structure should be of general utility for polycyclic aromatic hydrocarbons. UV, IR, and mass spectrometry were used to identify compound 10 as phenalenone. Although the neutral polar fraction of airborne particulate matter, which might be closely related in composition to the neutral polar fraction of carbon black, has been shown in possess considerable carcinogenic potency, concerted efforts have not been made to identify the polar compounds either in airborne particulates or carbon black. Screening the neutral polar compounds identified in carbon black for carcinogenic activity might be useful in discovering hitherto unsuspected environmental carcinogens.
Doi 10.1021/ac60358a002
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Language Text English
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