One-dimensional (1D) helical and 2D homochiral metal-organic frameworks built from a new chiral octahydrobinaphthalene-derived dicarboxylic acid
Ouyang, X; Chen, Z; Liu, X; Yang, Y; Deng, M; Weng, L; Zhou, Y; Jia, Y
| HERO ID | 615676 |
|---|---|
| In Press | No |
| Year | 2008 |
| Title | One-dimensional (1D) helical and 2D homochiral metal-organic frameworks built from a new chiral octahydrobinaphthalene-derived dicarboxylic acid |
| Authors | Ouyang, X; Chen, Z; Liu, X; Yang, Y; Deng, M; Weng, L; Zhou, Y; Jia, Y |
| Journal | Inorganic Chemistry Communications |
| Volume | 11 |
| Issue | 9 |
| Page Numbers | 948-950 |
| Abstract | Abstract: Three homochiral metal–organic frameworks (MOFs) based on enantiopure chiral ligand: (R)-2,2’-dimethoxy-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′-binaphthyl-3,3′-dicarboxylic acid (H2L), namely Cd(L)(Py)3 1, Cu(L)(Py)3 2, Na[Cd(L)(LH)]·2.5H2O 3 (Py=pyridine), were firstly synthesized, under solvothermal reactions. X-ray single-crystal diffraction studies reveal that 1 and 2 adopt one-dimensional (1D) infinite helical structures, while 3 possesses 2D chiral framework structure adopting ABAB offset stacking modes along the a-axis. Thermogravimetric analyses (TGA) display that 3 is thermally stable to 330°C which is rare for homochiral MOFs. [Copyright 2008 Elsevier] Copyright of Inorganic Chemistry Communications is the property of Elsevier Science Publishing Company, Inc. and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts) |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Keyword | DIFFRACTION; LIGHT; OPTICS; APODIZATION; DIFFRACTION loss; ELASTIC waves -- Diffraction |
| Is Qa | No |