Spectrophotometric determination of copper in alloys using naphthazarin

Chaisuksant, R; Palkawong-Na-Ayuthaya, W; Grudpan, K

HERO ID

644966

Reference Type

Journal Article

Year

2000

Language

English

PMID

18968145

HERO ID 644966
In Press No
Year 2000
Title Spectrophotometric determination of copper in alloys using naphthazarin
Authors Chaisuksant, R; Palkawong-Na-Ayuthaya, W; Grudpan, K
Journal Talanta
Volume 53
Issue 3
Page Numbers 579-585
Abstract Naphthazarin (5,8-dihydroxy-1,4-naphthoquinone; Naph) is proposed as a chromogenic reagent for the spectrophotometric determination of copper(II). The polynuclear complex has a mole ratio of Cu:Naph=4:6 in a 50% v/v ethanol/water medium containing 0.1 M ammonium acetate and 1.5% (w/v) sodium dodecyl sulfate. The copper-naphthazarin complex shows an absorption maximum at 330 nm with a molar absorptivity of 1.84x10(4) l mol(-1) cm(-1). Beer's law is obeyed up to 4.5 ppm of copper(II). The method was applied for copper determination in alloy samples with satisfactory results.
Pmid 18968145
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Language Text English
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