All-perylene-derivative for white light emitting diodes
Pereira-Andrade, E; Brum, SM; Policarpo, EMC; Gautam, SK; Plantevin, O; Lara, LRS; Stumpf, HO; Azevedo, GM; Mazzoni, MSC; Cury, LA; Malachias, A; Do Pim, WD; Sáfar, GAM; ,
| HERO ID | 6889923 |
|---|---|
| In Press | No |
| Year | 2020 |
| Title | All-perylene-derivative for white light emitting diodes |
| Authors | Pereira-Andrade, E; Brum, SM; Policarpo, EMC; Gautam, SK; Plantevin, O; Lara, LRS; Stumpf, HO; Azevedo, GM; Mazzoni, MSC; Cury, LA; Malachias, A; Do Pim, WD; Sáfar, GAM; , |
| Journal | Physical Chemistry Chemical Physics |
| Volume | 22 |
| Issue | 36 |
| Page Numbers | 20744-20750 |
| Abstract | An organic-based bright white light emitting compound, namely Tb(H3PTC)3 [H4PTC = perylene-3,4,9,10-tetracarboxylic acid], able to be used as part of a white diode and as a part of a RGB system that can withstand high temperatures (∼700 K), is developed using perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA) and terbium(iii) nitrate pentahydrate as precursors by hydrothermal synthesis. Using PTCDA as the red emitter and the new derivative of it, Tb(H3PTC)3, as the blue-green emitter, along with a common deep blue LED can form a RGB system for display technologies, around room temperature. Temperature-dependent photoluminescence properties of the Tb(H3PTC)3 compound are also investigated for the involved excitonic-emission processes and the respective recombination lifetimes. The terbium(iii) complex was prepared using a procedure that is reproducible, easily modifiable, inexpensive, and environmentally friendly, opening new pathways for its large-scale applications. Unlike PTCDA, Tb(H3PTC)3 has been shown to be soluble in N-methyl-2-pyrrolidone (NMP) as well as in dilute aqueous solutions of this organic solvent in a straightforward procedure. The light emission properties are intimately correlated with the molecular structure and electronic properties of Tb(H3PTC)3 elucidated by experimental results of X-ray Absorption Near Edge Spectroscopy (XANES), Extended X-ray Absorption Fine Structure (EXAFS) and Density Functional Theory (DFT) calculations. A bright fluorescence yield is attained with a small amount of material either in solution or in solid form showing its potential to be used in state-of-the-art organic optoelectronic devices. |
| Doi | 10.1039/d0cp02718a |
| Pmid | 32909018 |
| Wosid | WOS:000572458900049 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Language Text | English |