A co-reactant reverses relative reactivities

Laszlo, P; Montaufier, MT

HERO ID

854158

Reference Type

Journal Article

Year

1991

HERO ID 854158
In Press No
Year 1991
Title A co-reactant reverses relative reactivities
Authors Laszlo, P; Montaufier, MT
Journal Tetrahedron Letters
Volume 32
Issue 12
Page Numbers 1561-1564
Abstract The catalyzed benzoylation of anisole and mesitylene is slow (hours) in the 120 - 130-degrees-C temperature range. When the reactions are run separately, mesitylene reacts faster (by a factor three). However, when the two reactions are run jointly, competition favors anisole (also by a factor three).
Doi 10.1016/s0040-4039(00)74272-9
Wosid WOS:A1991FD47600009
Url http://linkinghub.elsevier.com/retrieve/pii/S0040403900742729
Is Certified Translation No
Dupe Override No
Is Public Yes
Keyword SELECTIVITY; INTERMOLECULAR; CO-REACTANT; FRIEDEL-CRAFTS; SYNERGY
Is Qa No