The interactions between axial and equatorial ligands in cobaloximes: NMR changes

Mandal, D; Chadha, P; Laskar, M; Bhuyan, M; Gupta, BD

HERO ID

854479

Reference Type

Journal Article

Year

2007

HERO ID 854479
In Press No
Year 2007
Title The interactions between axial and equatorial ligands in cobaloximes: NMR changes
Authors Mandal, D; Chadha, P; Laskar, M; Bhuyan, M; Gupta, BD
Journal Tetrahedron Letters
Volume 48
Issue 13
Page Numbers 2377-2379
Abstract All three methyl groups in mesitylene become nonequivalent in the H-1 NMR spectra of PhCH2Co(dmestgH)(2)Py, PhCH2(SO2)Co(dmestgH)(2)Py, and PhCH2(O-2)CO(dmestgH)(2)Py, due to weak interactions between the axial benzyl and the equatorial dioxime ligands. (c) 2007 Elsevier Ltd. All rights reserved.
Doi 10.1016/j.tetlet.2007.01.140
Wosid WOS:000245388700034
Url http://linkinghub.elsevier.com/retrieve/pii/S0040403907002080
Is Certified Translation No
Dupe Override No
Is Public Yes
Keyword cobaloximes; dimesitylglyoxime; nonequivalence; weak interaction
Is Qa No