Formation of manganese–alkyne complexes mediated by trialkylmanganates and their application
Nishikawa, T
| HERO ID | 854518 |
|---|---|
| In Press | No |
| Year | 2003 |
| Title | Formation of manganese–alkyne complexes mediated by trialkylmanganates and their application |
| Authors | Nishikawa, T |
| Journal | Tetrahedron |
| Volume | 59 |
| Issue | 48 |
| Page Numbers | 9661-9668 |
| Abstract | Treatment of dodec-6-yne with triallylmanganate in the presence of 1,3,5-trimethylbenzene provides (Z)-dodec-6-ene. An addition of D2O before quenching the reaction affords the corresponding dideuterated alkene. The result suggests the existence of the manganese-alkyne complex as an intermediate. Treatment of methyl propargyl ethers as alkynes with tributylmanganate generates propargylmanganese species. The reaction of non-2-ynyl tetrahydropyran-2-yl ether with tributylmanganate provides tetradec-7-yn-1,5-diol and 6-hexylocta-6,7-dien-1,5-diol. (C) 2003 Elsevier Ltd. All rights reserved. |
| Doi | 10.1016/j.tet.2003.09.077 |
| Wosid | WOS:000186617600020 |
| Url | http://linkinghub.elsevier.com/retrieve/pii/S0040402003015345 |
| Is Certified Translation | No |
| Dupe Override | No |
| Is Public | Yes |
| Keyword | manganese-alkyne complex; diyne; tetrahydronaphthalene; allylation; acetals |
| Is Qa | No |